| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 가을 (11/12 ~ 11/14, 엑스코(대구)) |
| 권호 |
18권 2호 |
| 발표분야 |
(국제협력위원회)우수 외국인 연구자를 위한 세션 |
| 제목 |
High catalytic performance of nanocrystalline Zr1-xNixO2 catalysts for selective CO methanation |
| 초록 |
Ni/ZrO2 catalysts have been proposed as a promising candidate for CO removal from reformed fuels via selective CO methanation (CO-SELMET). In this work, we have investigated the catalytic performance of nickel substituted zirconia derived from nanocrystalline powders for CO-SELMET with compositions 0≤x≤0.7 in Zr1-xNixO2. Nanoparticles of Zr1-xNixO2 were synthesized by urea-nitrate combustion method. The combustion method was found to be a simple and fast route for the synthesis of ultrafine, nanocrystalline Zr1-xNixO2 catalysts. The catalytic performance of the prepared catalysts have been tested in a micro fixed-bed reactor. Based on the experimental results, the influence of the urea/nitrate ratio and the Ni content on the catalytic properties of Zr1-xNixO2 catalysts has been studied and optimized. Compared with ordinary Ni/ZrO2 catalysts, the prepared catalysts have exhibited good catalytic performance and stable for CO-SELMET. |
| 저자 |
K. Khaja Mohaideen, 김우현, 구기영, 윤왕래
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| 소속 |
한국에너지기술(연) |
| 키워드 |
CO methanation; Nickel; Zirconia; Solution combustion method
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| E-Mail |
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