화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2020년 가을 (10/28 ~ 10/30, 광주 김대중컨벤션센터(Kimdaejung Convention Center))
권호 24권 1호
발표분야 포스터-콜로이드·계면화학
제목 Bacterial cellulose nanofibrils-armored Pickering emulsions with limited influx of metal ions through the oil-water interface
초록 This study introduces a novel UV-blocking Pickering emulsion system of which solid interface consisted of a bacterial cellulose nanofibril (BCNF) surfactant. For this, we prepared TEMPO-oxidized BCNFs and their surface was hydrophobically modified by covalently grafting controlled amounts of C18 alkyl chains. We observed that this BCNF surfactant reduced the surface tension while forming a cellulose membrane at the oil-water (O/W) interface. This cellulose membrane stabilized Pickering emulsion by armoring oil drops. The BCNF surfactant was feasible to emulsify up to 40 vol% of oil. We showed that the BCNFs were able to entrap metal ions by electrostatic binding between BCNFs and metal ions which is essential for the emulsion to maintain UV-blocking performance. Finally, we expect that the BCNFs fabricated in this study would have great applicability either for development of a variety of cellulose surfactant or for the application of UV-blocking Pickering emulsions.
저자 서혜민, 김진웅
소속 성균관대
키워드 cellulose nanofibrils; Pickering emulsion; interfacial membrane; UV-blocking
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