화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2014년 가을 (11/12 ~ 11/14, 엑스코(대구))
권호 18권 2호
발표분야 환경에너지-포스터
제목 Ethanol dehydration on hybridized zeolites with Ferrierite and ZSM-5
초록 Ethylene has been largely used in the petrochemical industries for the preparation of polyethylene, ethylene oxide, ethylene dichloride, etc. In addition, diethylether(DEE) has been recently reported as an oxygenated additive for diesel fuel to alleviate NOx emission. In the present study, the hybridized zeolites were prepared by using two different zeolites of Ferrierite and ZSM-5 by changing the synthesizing orders and the catalysts were tested for the dehydration of ethanol. Type (I) catalyst was synthesized by adding previously prepared H-Ferrierte during ZSM-5 synthesis, and type (II) was synthesized by adding H-ZSM-5 during Ferrierite synthesis. The conversion of ethanol and product distribution were measured to verify the preparation methods of hybridized zeolites, and NH3-TPD, power XRD and BET analysis were used to characterize the physicochemical properties of zeolites.
저자 박소영, 배종욱
소속 성균관대
키워드 Ethanol dehydration; Hybridized zeolite; Diethyl ether (DEE); Ethylene; Ferrierite; ZSM-5
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