화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 기능성 고분자
제목 Measurement of Water Vapor Permeation of Epoxy Functionalized Organic-Inorganic Hybrid Materials (Epoxy Hybrimers) for Application in Gas Barrier Coating
초록 OLED has been attracted attention for the next generation display. However, their disadvantages are restricted in applications due to their high gas permeation. Thus, many researchers have tried to fabricate high performance gas barrier materials. Inorganic materials have excellent barrier properties but they also have many defects. Consequently, polymer and inorganic multi-layers (dyads) was used for high performance gas barrier films. In this study, we synthesized the epoxy hybrimers which consist of siloxane networks and organic functional groups using non-hydrolytic sol-gel reaction. We measured the permeability of the epoxy hybrimer film for oxygen and water using Ca test method which measure resistivity change of Ca layer. The epoxy hybrimers show excellent barrier properties because of inorganic networks, hydrophobicity and high density of the cured films. They also show high photosensitivity, transmittance and smooth surface to be applied practically in various fields.
저자 정경호, 김준수, Haibo Zhang, 배병수
소속 KAIST
키워드 barrier; gas permeation; water vapor transition rate (WVTR); organic-inorganic hybrid materials; sol-gel
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