| 학회 |
한국공업화학회 |
| 학술대회 |
2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO)) |
| 권호 |
21권 2호 |
| 발표분야 |
촉매_포스터 |
| 제목 |
Room-temperature synthesis of cyclic carbonates using a non-interpenetrated metal organic framework assisted by ammonium halides |
| 초록 |
A zinc containing 3D non-interpenetrated metal organic framework, UMCM-15 was found to display excellent synergistic catalysis with alkyl ammonium halides (TBAX) in the room temperature fixation of CO2 with epoxide to cyclic carbonate. The favorable role of non-interpenetrated pillared structures in promoting room temperature CO2-epoxide cycloaddition reactions was explained by comparing the catalytic efficiency of the three-linker extended pillar-layered non-interpenetrated UMCM-15 with its analogous pillared structures built from two- and three-fold interpenetrated ([Zn2(BDC)2(4,4'-bipy)] and [Zn2(NDC)2(4,4'-bipy)]) catalytic systems with a single dicarboxylate linker. Reaction parameters were optimized by altering the conditions. In addition, a plausible mechanism for the synergistic operation of the Lewis acid sites and nucleophiles was suggested. |
| 저자 |
Robin Babu, 박대원, 김설희, Jintu Francis K
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| 소속 |
부산대 |
| 키워드 |
Aqueous microwave synthesis; UMCM-15; TBAB; CO2; epoxide; cyclic carbonate.
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| E-Mail |
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