학회 | 한국고분자학회 |
학술대회 | 2002년 봄 (04/12 ~ 04/13, 서울대학교) |
권호 | 27권 1호, p.189 |
발표분야 | 특별 심포지엄 |
제목 | The Characteristics of Organo-Montmorillonite/NBR Nanocomposites with Silane Coupling Agent |
초록 | In this study, C18-MMT/NBR/coupling agent nanocomposites were prepared by a melt intercalation process at 50∼60℃. During the melt compounding, organo-montmorillonite(MMT) particles were clearly observed that had been exfoliated into nanoscale layers with about 10∼20 nm thickness from their original 40μm particle size and these MMT layers were dispersed in NBR matrix uniformly. The effects of coupling agent such as 3-(mercaptopropyl)trimethoxy silane in the C18-MMT/NBR nanocomposite had been studied. The C18-MMT/NBR nanocomposites in presence of coupling agent were characterized by X-ray diffraction, transmission electron microscopy, universal testing machine(UTM), thermogravimetric analysis and infrared spectroscopic. It is observed that addition of the silane coupling agent, 3-(mercaptopropyl)trimethoxy silane, enhances the chemical interaction with the formation of coupling bonds of Si-O-Si type between C18-MMT and coupling agent and Si-C bonds between NBR and the coupling agent. The above improved properties are due to nanoscale effects and strong interaction of coupling bonds between NBR and organo-montmorillonite |
저자 | 김진태1, 오택수2, 이동호*3 |
소속 | 1포항산업과학(연), 2금속코팅재료연구팀, 3*경북대 |
키워드 | |