학회 |
한국고분자학회 |
학술대회 |
2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터) |
권호 |
44권 2호 |
발표분야 |
기능성 고분자 |
제목 |
Preparation and properties of poly (urethane acrylate) film using UV curing systems |
초록 |
Two types of UV‐curable polyurethane acrylate (PUA) prepolymers were synthesized by using toluene‐2,4‐diisocyanate (TDI) or isophorone diisocyanate (IPDI) with polycaprolactone diol (PCLD). The prepolymers subsequently reacted with 2- hydroxyethyl methacrylate. The structure of PUA was characterized by Fourier transform infrared spectroscopy. The PUA mixed with trimethylol propane triacrylate (TMPTA) and 1,6-hexanediol diacrylate (HDDA). The mechanical properties, thermal properties, and optical properties of the cured mixtures film were investigated. In comparison with PUA mixture film using PCLD–IPDI (P-I film), PUA mixture film with PCLD-TDI (P-T film) showed relatively high thermal decomposition temperatures and tensile strength. Also, we confirmed an increase in the yellowness index of P-T film in comparison with one P-I film. |
저자 |
김정수1, 홍석주1, 신우승1, 김유진1, 임승호1, 권용록1, 최준1, 이윤석2, 김동현1
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소속 |
1한국생산기술(연), 2연세대 |
키워드 |
PUA; IPDI; TDI; film; UV curing
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E-Mail |
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