화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 기능성 고분자
제목 Preparation and properties of poly (urethane acrylate) film using UV curing systems
초록 Two types of UV‐curable polyurethane acrylate (PUA) prepolymers were synthesized by using toluene‐2,4‐diisocyanate (TDI) or isophorone diisocyanate (IPDI) with polycaprolactone diol (PCLD). The prepolymers subsequently reacted with 2- hydroxyethyl methacrylate. The structure of PUA was characterized by Fourier transform infrared spectroscopy. The PUA mixed with trimethylol propane triacrylate (TMPTA) and 1,6-hexanediol diacrylate (HDDA). The mechanical properties, thermal properties, and optical properties of the cured mixtures film were investigated. In comparison with PUA mixture film using PCLD–IPDI (P-I film), PUA mixture film with PCLD-TDI (P-T film) showed relatively high thermal decomposition temperatures and tensile strength. Also, we confirmed an increase in the yellowness index of P-T film in comparison with one P-I film.
저자 김정수1, 홍석주1, 신우승1, 김유진1, 임승호1, 권용록1, 최준1, 이윤석2, 김동현1
소속 1한국생산기술(연), 2연세대
키워드 PUA; IPDI; TDI; film; UV curing
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