화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 분자전자 부문위원회 Ⅰ,Ⅱ
제목 Effect of Electron Withdrawing Groups on Triphenylamine-Substituted Quinoxaline-based D-A type Conjugated Polymers
초록 In this study, two D-A type polymeric backbone was constructed by coupling of the electron-donating chlorinated-benzodithiophene (BDT) and the electron-accepting triphenylamine-substitued quinoxaline derivatives. In addition, the strong electron-withdrawing fluorine atom and cyano unit were selectively incorporated into the quinoxaine moeity to investigate their effects on the photovoltaic properties of the polymers. After confirming the polymer properties, the photovoltaic properties of the polymers were investigated by fabricaitng the inverted-type device with the configuration of ITO/SnO/Polymers:Y6/MoO3/Ag. Interestingly, the photovoltaic properties of the polymers are strongly dependent on the type of the electron-withdrawing substituents in their structures. Therefore, this study can offer meaningful insights in the structure-property relationships of conjugated polymers for developing high performance polymer solar cells.
저자 Dinda Fariesta Nugraha1, 김은영2, 장동욱2
소속 1Pukyong National Univ., 2부경대
키워드 Quinoxaline; Photovoltaic device; Donor
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