| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 가을 (10/10 ~ 10/11, 부경대학교) |
| 권호 |
28권 2호, p.119 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
A Study on Curing and Swelling Behaviors of Epoxy(DGEBA)/Amine(TETA) System |
| 초록 |
We observed the curing behavior of diglycidyl ether of bisphenol A (DGEBA)/triethylenetetramine (TETA) system using real-time infrared spectroscopy (RTIR) and dynamic mechanical thermal analysis (DMTA), and investigated the swelling behavior of the crosslinked specimens for the system by determining volume swelling ratio (Q) according to the swelling time. RTIR analysis showed that the curing reaction of DGEBA epoxy and TETA amine was a more predominant reaction compared to the homopolymerization of epoxy itself by observing 914 and 1121 cm-1 bands of DGEBA epoxy peak. DMTA experiments revealed that the crosslink density of DGEBA/TETA system increased as the content of TETA was increased. The swelling experiments exhibited that initial swelling rate increased and then rapidly reached to equilibrium state with increasing the content of TETA.
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| 저자 |
Jung-Dae Cho1, Hyoung-Tae Ju2, Seung-Taek Han3, Jae-Sung Lee4, Jin-Who Hong1
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| 소속 |
1Department of Polymer Science & Engineering, 2Chosun Univ., 3Gwangju 501-759, 4South Korea |
| 키워드 |
curing behavior; swelling behavior; RTIR spectroscopy; DMTA
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| E-Mail |
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