| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 가을 (10/06 ~ 10/08, 제주 ICC) |
| 권호 |
39권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Ethylene tetramerization with Chromium piperidine PNP catalyst |
| 초록 |
1-Hexene and 1-octene are very important and highly demanding comonomers used for the synthesis of linear low-density polyethylene (LLDPE). But they are mainly produced by conventional ethylene oligomerization process like Shell Higher Olefin Process (SHOP), which yield a full range of linear α-olefins based on Schultz–Flory distribution, and have to be isolated through inefficient process. Therefore, a lot of effort has been devoted to achieve a selective tri- or tetramerization of ethylene and Sasol company reported an tetramerization reaction that produces1-octene in good selectivity. In this study, we synthesized novel chromium piperidine PNP catalyst and investigated their ethylene oligomerization behavior. |
| 저자 |
정태욱1, 사석필2, 이용호2, 신은지2, 조민석2, 김상율1
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| 소속 |
1KAIST, 2LG Chem |
| 키워드 |
Ethylene tetramerization; 1-octene; Chromium piperidine PNP catalyst
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| E-Mail |
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