화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2003년 가을 (10/24 ~ 10/25, 한양대학교)
권호 9권 2호, p.1610
발표분야 고분자
제목 Retinoid separation characteristics of molecular imprinted poly(methacrylic acid) beads prepared via suspension polymerization
초록 The suspension polymerization that uses perfluorocarbon liquid as the dispersing phase is promising to provide recognition sites because it gives no interaction between functional monomers or template and dispersing agent during molecular imprinting. The monomer of methacrylic acid (MAA) was cosslinked with ethylene glycol dimethyacrylate (EGDMA) in the presence of a template of all trans-retinoic acid to prepare molecular imprinted polymers. The prepared molecular imprinted polymer beads showed good performance in the HPLC separation of retinoid derivatives. Specific interactions such as hydrogen bonding and ion-pair interactions were the main functions for separation of objective molecules.
저자 김가연, 김덕준
소속 성균관대
키워드 Molecular imprinting; Template; Stationary phases; Chromatography
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