화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2004년 봄 (04/23 ~ 04/24, 공주대학교)
권호 10권 1호, p.855
발표분야 재료
제목 Preparation of Shape-anisotropic Building Blocks for Photonic Crystals
초록 Self-assembly method for the preparation of photonic bandgap materials has attracted great attention after pioneering work by Yablonovich in 1987. A number of colloidal crystallization methods of monodisperse microspheres have been developed in association with the self-assembly approaches for nanotechnology. Despite unique optical properties of colloidal crystals or their inverted structures, realization of a complete photonic bandgap is still difficult due to the symmetry of photonic crystal lattices. To address this problem, theoretical calculations for the introduction of asymmetry in the lattice of a photonic crystal have been conducted and ellipsoidal polystyrene lattice was prepared by Xia et al. to reduce the symmetry of opaline lattice. However, only lattice spacing between (111) planes of colloidal crystal could be changed. In this study, compressive stress was applied to prepare disk-shaped polystyrene colloidal crystals infiltrated with poly(dimethylsiloxane) aligned along (111) direction of opaline lattice. Scanning electron microscopy was used to observe the deformed shape of composite colloidal crystal. The reflectance spectra of were obtained to observe the change of pseudo-gap with the spectra of the original composite film.
저자 조영상, 문준혁, 양승만
소속 한국과학기술원 생명화학공학과
키워드 Photonic bandgap materials; Shape-anisotropic colloidal crystal; Asymmetry in opaline lattice
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