| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
정밀화학_포스터 |
| 제목 |
A New Dicyanomethylidene isoporone Based Colorimetric & Fluorometric Sensor for F- and Hg+ |
| 초록 |
We have synthesized a new colorimetric and fluorometric “turn on” sensor which based on the thiophosphinate derivative with Dicyanomethylidene isophorone group (sensor 1). The sensor 1 showed high selectivity and sensitivity towards F- and Hg+ in DMSO/H2O(v/v = 7:3, pH = 8.03). It displays a 30 nm red-shift of maximum absorption band with color change from pale yellow to deep yellow upon addition of F- and Hg+. And the fluorescence emission intensity increased upon addition of F-, Hg+. The ions(F-, Hg+) selective signaling of sensor 1 did not undergo interference in the presence of other common background ions. Furthermore sensing mechanism of 1+F- was property identified from 1H NMR study. |
| 저자 |
전근1, 김성훈2, 조찬식2, 안경룡1, 조지영1
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| 소속 |
1한국화학(연), 2경북대 |
| 키워드 |
sensor; thiophosphinate; fluoride; mercury
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| E-Mail |
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