| 학회 | 한국공업화학회 |
| 학술대회 | 2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 | 8권 2호 |
| 발표분야 | 고분자 |
| 제목 | Facilitated Transport Mechanism of Propylene in Polymer Electrolyte Membranes Containing Silver Salts |
| 초록 | The two step reaction mechanism between silver ion and propylene has been proposed previously: complexation and exchange reactions. It is expected that the exchange reaction, in particular, plays a major role in determining the facilitated transport. Hence, the facilitated olefin transport has been modeled mathematically. (1) (2) (3) The exchange reaction rate cannot be expressed implicitly, but by finite difference equation instead because the reactants and products in equation (2) are the same. The effects of parameters, D, K, k1 and ke in the model on the facilitated transport will be evaluated. Furthermore, the model will be attempted to fit the experimental sorption data by Quartz Crystal Microbalance. The validity of the model will also be evaluated. |
| 저자 | 고동균, 이경민, 이귀종, 강용수 |
| 소속 | 한국과학기술(연) |
| 키워드 | facilitated transport mechanism; exchange reaction |
