화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.2652
발표분야 분리기술
제목 Molecular Weight Distributions and Components of Heat Reformed Naphtha Cracking Bottom Oil Extracts
초록 Naphtha Cracking Bottom (NCB) oil was heat reformed at various reforming temperature and time, and the volatile extracts were characterized including yields, molecular weight distributions, and representative compounds. The yield of extract increased as the increase of reforming temperature(360-420℃) and time(1-4hr). Molecular weight of the as-received NCB oil was under 370 mass, and those of extracts were distributed in the range of 200-320 mass, and far smaller than those of precursor pitches in 380-550. As GC-ms results, it was almost found out aromatic compounds in extract. Representative compounds in extracts were naphthalene, styrene, indene, biphenyl, acenaphthene, flourene and phenanthrene. Most of compounds were isomers of compounds bonding functional groups, such as methyl(CH3-) and ethyl(C2H5-). Especially, main naphthalene existed in every extract.
저자 이재영1, 이태형2, 유승곤1
소속 1충남대, 2(주)테크노세미켐
키워드 NCB oil; extract; molecular weight distribution
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