학회 | 한국고분자학회 |
학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
권호 | 27권 2호, p.291 |
발표분야 | 기능성 고분자 |
제목 | The fluorescence-quenching effect of a new water-soluble polybenzimidazole by bipyridine |
초록 | Water-soluble conjugated polymer sensors using a fluorescence-quenching effect by methyl viologen (MV2+) have been one of the most attracting research fields. The quenching result from the electron transfer from excitations on the polymer chain to the acceptor. Until now, many PPV derivatives have been studied for the chemosensor. Though PPV have led to development of a new class of fluorescence-based sensors, they still have several problems such as the uncertain quenching mechanism, low fluorescence and quenching efficiencies. In this presentation, we report a new water-soluble polybenzimidazole having a fluorene group in the backbone. The synthesized water-soluble polymer shows good quenching efficiency and is expected to have improved properties such as a high PL quantum yield. Details of synthesis, structural characterization and photophysical properties of the polymers will be presented. |
저자 | 최호욱, 양남철, 김윤석, 이영식, 서동학 |
소속 | 한양대 |
키워드 | polybenzimidazole; fluorescence; sensor |