화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 가을 (11/12 ~ 11/14, ICC 제주)
권호 12권 2호
발표분야 고분자
제목 Preparation of Crosslinked PE Separator for Lithium Ion Battery by EB Irradiation
초록 In this paper, to study the irradiation effect of polyethylene (PE) separator for lithium ion battery, commercial PE separators (SK (12, 20, and 25m)) were irradiated by electron beam (EB) at 50, 100, 150, and 200 kGy, respectively. The degree of crosslinking of EB-irradiated PE separators increased with an increase in the absorption dose of the electron beam. Mechanical and thermal properties of the irradiated PE separators were evaluated by UTM and DMA. The effect of EB irradiation on the electrochemical properties of the prepared separators, such as the ionic conductivity and shutdown function was studied by electrochemical AC-impedance spectroscopy. The results showed that the EB-irradiated separators had better modulus, heat resistance and shutdown behaviors than the non-irradiated PE separator.
저자 임종수1, 손준용2, 권성진1, 신준화2, 최재학2, 김정수1, 노영창2
소속 1충남대, 2한국원자력(연)
키워드 electron beam irradiation; separator; shutdown; lithium secondary battery
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