화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1793
발표분야 열역학
제목 Effects of promoter on the formation of gas hydrate from Blast Furnace Gas
초록 The effect of various promoters was investigated for CO2 separation from the flue gas of steel-making process using gas hydrate technology. The studied promoters are tetrahydrofuran (THF), propylene oxide and 1,4-dioxane, which are all expected to form a structure II hydrate, and the target gases are CO2/N2 mixed gases (CO2/N2 = 20/80 and 40/60) and Blast Furnace Gas (BFG). The composition of BFG is (CO2 : CO : H2 : N2 = 20 : 23.8 : 3.5 : 52.7). The phase equilibrium conditions of gas hydrate were measured for each gas when each promoter was added with various concentrations. For fast acquisition of abundant data, the “continuous” Quartz crystal microbalance (QCM) method was employed. In addition, the crystal structure of each gas hydrate was analyzed by Powder X-ray diffraction (PXRD).
저자 곽계훈1, 사정훈1, 김시환2, 이보람3, 이건홍1
소속 1포항공과대, 2포항산업과학(연), 3Colorado School of Mines
키워드 gas hydrates; CO2 separation; promotion effect; Blast Furnace Gas (BFG)
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