| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
분자전자 부문위원회 II |
| 제목 |
Control of Molecular Packing Orientations of Thieno-Benzo-Isoindigo-Based Polymers through Modulating Thin-Film Fabrication Condition |
| 초록 |
Polymers with high performance organic field-effect transistors (OFETs) characteristics usually show preference for edge-on packing orientation. From face-on orientation-dominant thieno-benzo-isoindigo (TBIG), which is one of the isoindigo (IIG) derivatives, we devote our attention to elicit edge-on orientation by modulating thin-film fabrication condition. Grazing-incidence X-ray diffraction (GIXD) analysis results show the TBIG polymer thin-films with rapid solvent evaporation demonstrate more intense π-π spacing peaks near the qxy plane due to in-plane π-stacking. At least twice higher hole mobility is achieved with in-depth control of solution-process condition and this result opens the possibility of molecular packing orientation control without exacting synthetic strategies. |
| 저자 |
오준학1, 양창덕2, 이정호2, 한아름2, 이해랑1
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| 소속 |
1포항공과대, 2울산과학기술대 |
| 키워드 |
organic field-effect transistor; polymer semiconductor; packing orientation
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| E-Mail |
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