화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 기능성 고분자
제목 Fabrication of the Cross-linked Polysiloxane Network Containing POSS Side Chain.
초록 Polyhedral oligomeric silsesquioxane(POSS) has been incorporated into various polymers to make hybrid materials. POSS with rigid silica-like core has a high thermal and mechanical properties. Polymethylhydrosilxane(PMHS)-based electrolyte has been popular for lithium ion polymer electrolyte application. In this study, allyl-POSS was synthesized by the corner-capping reaction of incompletely condensed silsesquionxane and allyl trichlorosilane. Polysiloxane with POSS side chain was prepared by the hydrosilylation reaction of PMHS and Allyl-POSS under Pt catalyst. The obtained polysiloxane with POSS side chain was used to make cross-linked polysiloxane network having POSS units with diallyl poly(ethylene glycol) cross-linking reagent.
저자 김성관, 임정혁, 김경민
소속 한국교통대
키워드 POSS; electrolyte; cross-linked polymer; polysiloxane
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