| 학회 |
한국화학공학회 |
| 학술대회 |
2006년 봄 (04/20 ~ 04/21, 대구 인터불고 호텔) |
| 권호 |
12권 1호, p.273 |
| 발표분야 |
분리기술 |
| 제목 |
Influence of Adsorption Properties on the Heterogeneous Photocatalytic Oxidation Rate of 2,4,6-Trinitrotoluene(TNT) |
| 초록 |
The influence of adsorption on the kinetics on the photocatalytic degradation of 2,4,6-trinitrotoluene (TNT)was investigated. The effects of various parameters such as temperature, the initial TNT concentration, the initial pH and TiO2 dosage, and the light intensity of UV lamp on the TNT degradation rate by TiO2 photocatalysis were examined. The reaction rate was found to obey pseudo second-order kinetics represented by the Langmuir-Hinshelwood kinetic expression. The values of the adsorption equilibrium constant (KTNT) and the second-order rate constant (kc) were determined to analyze the effect of adsorption properties on the heterogeneous photocatalytic oxidation rate. It was found that the photocatalysis rate of TNT was highly dependent on the initial concentration and temperature. |
| 저자 |
황경준1, 이재욱1, 이민주2, 양태훈1, 문일식3
|
| 소속 |
1서남대, 2전남대, 3순천대 |
| 키워드 |
Adsorption; Trinitrotoluene; photocatalytic; TiO2
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| E-Mail |
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| 원문파일 |
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