화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 봄 (04/27 ~ 04/29, 부산 BEXCO)
권호 22권 1호, p.52
발표분야 고분자
제목 A Green Approach of Preparing Graphene/Polyaniline Electrodes for Supercapacitors
초록 Biodegradable chitosan modified graphene/polyaniline nanocomposites was prepared by using modified Hummer’s method from graphite flakes. Physical adsorption of chitosan on exfoliated graphene oxide (GO), further reduced by hydrazine hydrate and in-situ polymerized in the presence of aniline monomer.  
Graphene has attracted much attention in electrochemical supercapacitors due to its exceptional qualities. However graphene tends to aggregate and restack after reduction, resulted in significant decrease in the surface, consequently leading to poor capacitor performance. Chitosan, a biodegradable linear polysaccharide, acts as a stabilizer to reduce restacking and helps well-dispersion of the graphene sheets after reduction. Polyaniline (PANI) is a promising electrode because of its relatively high conductivity regardless with low cycle life. The combination of high conductive PANI with chitosan modified well-dispersed graphene sheet offers to maximize the capacitance. Acknowledgment  
This study was supported by the National Research Foundation of Korea (grant no.: 2013R1A2A2A04013913 and 2015R1A4A1042434).
저자 K Zin Htut, 김민재, 이은수, 심상은
소속 인하대
키워드 고분자복합재료; 바이오고분자
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