| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Ethylene Oligomerization with Chromium Phenylene-Bridged SNS Catalytic System |
| 초록 |
1-Hexene and 1-octene are very important and highly demanding comonomers used for the synthesis of linear low-density polyethylene (LLDPE). But they are mainly produced by conventional ethylene oligomerization process like Shell Higher Olefin Process (SHOP), which yield a full range of linear α-olefins based on Schultz–Flory distribution, and have to be isolated through inefficient process. Therefore, a lot of effort has been devoted to achieve a selective tri- or tetramerization of ethylene. McGuinness and coworkers reported that tridentate SNS systems showed the high selectivity of 1-hexene and good activity. In this study, we synthesized novel chromium phenylene-bridged SNS complexes and investigated their ethylene oligomerization behavior. |
| 저자 |
정태욱1, 사석필2, 이용호2, 신은지2, 조민석2, 김상율1
|
| 소속 |
1KAIST, 2LG 화학 |
| 키워드 |
Ethylene Oligomerization |
| E-Mail |
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