화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 기능성 고분자 (포스터발표만 진행)
제목 Fabrication of SiO2 Nanopatterns Based on Si-Containing Block Copolymer Self-Assembly
초록 Templated self-assembly of a lamellar-forming polystyrene-block-poly(4-(tert-butyldimethylsilyl)oxystyrene) (PS-b-PSSi) diblock copolymer has been investigated for nanolithography. Nanopatterns with various line widths were fabricated with different molecular weights. Since organic-inorganic block copolymers have a large difference in etch resistance between the organic and inorganic blocks, sub-20-nm lines of silicon oxide can be directly produced upon oxygen plasma treatment. Orientation of lamellar nanodomains was manipulated simply by adjusting the relative composition of selective and non-selective solvents in the annealing solvent. The use of a PS-brush treated substrate is especially advantageous for achieving long-rage ordering and minimizing defect densities, and the Si content in PSSi leaves a robust oxide etch mask after one-step reactive ion etching. This block copolymer system can be applied to the nanopatterning processes that require high aspect ratio structures.
저자 박창홍, 강은희, 김진백
소속 한국과학기술원
키워드 nanopatterns; self-assembly; block copolymer
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