| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Preparation and Characterization of Poly(2-ethynyl-N-pentylpyridinium iodide)-Iron(III) Chloride Composite |
| 초록 |
A new polyacetylene, poly(2-ethynyl-N-pentylpyridinium iodide), was easily prepared by the spontaneous polymerization of 2-ethynylpyridine using 1-iodopentane without any additional catalyst. The ionic conjugated polymer-iron(III) chloride composites were prepared by the complexation of the resulting polymer and iron(III) chloride in DMF. The electrical conductivity of polymer-iron(III) chloride composite was measured. The photoluminescence (PL) spectra of polymer-iron(III) chloride composite showed that the photoluminescence peak is located at 578 nm, corresponding to a photon energy of 2.15 eV. The cyclic voltammograms of polymer-iron(III) composite exhibited irreversible electrochemical behaviors between the doped and undoped peaks. It was found that the kinetics of the redox process of polymer is controlled by the reactant diffusion process. |
| 저자 |
이지원1, 제갈영순2, 진성호3, 임권택4, 박종욱1
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| 소속 |
1가톨릭대, 2경일대, 3부산대, 4부경대 |
| 키워드 |
Conjigated polymer; 2-ethynylpyridine; composite; iron(III) chloride; cyclovoltammogram
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| E-Mail |
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