초록 |
Although the study of supramolecular polymers has made considerable progress, it remains a challenge to realize control over supramolecular polymerization. In this presentation, I will introduce two strategies to fabricate supramolecular polymers, leading to advancement of controlled supramolecular polymerization. One is multi-step self-assembly, which includes covalent preparation of ditopic monomers and supramolecular polymerization of the ditopic monomers. Another method involves so-called mixed strategy, including non-covalent preparation of supramonomers and covalent polymerization or supramolecular polymerization of the supramonomers. It is highly anticipated that these studies will enrich the methodology of supramolecular polymerization, which may be used for fabricating supramolecular polymer materials with controlled molecular weight and architectures. |