학회 |
한국화학공학회 |
학술대회 |
2003년 봄 (04/25 ~ 04/26, 순천대학교) |
권호 |
9권 1호, p.822 |
발표분야 |
열역학 |
제목 |
Measurement of vapor-liquid equilibria for the binary mixture of propylene(R-1270) + HFC-134a |
초록 |
Isothermal vapor-liquid equilibria data for the binary mixture of propylene (R-1270) + HFC-134a at five equally spaces temperatures between 273.15 and 313.15K were measured by using a circulation-type equilibrium apparatus. The experimental data were correlated with the Peng-Robinson equation of state (PR-EOS) combined with the Wong-Sandler mixing rule. It was confirmed that the data calculated by this equations of state have a good agreement with experimental data. The experimental azeotropic points at investigated temperatures of this mixture were compared with ones calculated from the simple equation gotten from the fundamental equation of phase equilibrium and NRTL activity coefficient model. The result indicates that there was a small different between experimental azeotropic points and calculated ones corresponding to nonrandomness parameter α12 equaling to 0.2. |
저자 |
호광누, 이병권, 박지영, 임종성
|
소속 |
한국과학기술(연) |
키워드 |
Vapor-liquid equilibria; Propylene; HFC-134a
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E-Mail |
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