| 학회 |
한국공업화학회 |
| 학술대회 |
2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
22권 2호 |
| 발표분야 |
(국제협력위원회) 우수외국인연구자세션 |
| 제목 |
Highly active and stable zirconium phosphate grafted on silica for renewable p-xylene production from biomass-derived intermediates |
| 초록 |
A biorefinery technology is an important approach for the production of renewable energy and chemical building blocks. Among them, p-xylene (PX) has been considered as an important building block for terephthalic acid that can be used as monomer for polyester and polyethylene terephthalate plastics. In the present study, one-pot grafting method of zirconium phosphate (ZrP) on different silica-based supports were studied for PX production from 2,5-dimethylfuran (DMF) with ethylene through cycloaddition reaction. The ZrP grafted on SBA-15 (ZrP-SBA-15) displayed a maximum DMF conversion of 89% with 95% selectivity of PX, which was significantly higher than the ZrP on ordered KIT-6 and commercial SiO2 support. The high catalytic performance for PX production on the ZrP-SBA-15 may be attributed to the different surface structures of ZrP phases on the SBA-15 with its optimal acidic site density, which were confirmed by solid-state 31P NMR. |
| 저자 |
saravanan Kasipandi, 조재민, 배종욱
|
| 소속 |
성균관대 |
| 키워드 |
Zirconium phosphate; Silica; p-Xylene; Sustainable chemistry
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| E-Mail |
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