| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터) |
| 권호 |
46권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Solvent-free Acrylic Pressure-Sensitive Adhesives via an Additive-free Visible-light Driven Photocatalytic Free Radical Polymerization |
| 초록 |
Solvent-free light-curing acrylic pressure-sensitive adhesives (PSAs) have tremendously grown but mostly prepared in the presence of photoinitiators by high-energy UV-light that causes several issues such as radiation safety. Herein, for the first time, solvent-free acrylic PSAs were prepared through visible-light-driven photocatalytic free radical polymerization. Combined experimental and theoretical studies show that the use of N-vinyl based monomer is essential to enhance the polymerization rate and monomer conversion. Viscoelasticity, mechanical strength and adhesion performance of acrylic PSAs were nicely adjusted in a broad range by controlling the monomer composition, suggesting that our new method would replace the existing photoinitiated free radical polymerization. |
| 저자 |
백종호1, 권용환2, Juan Carlos Roldao3, 유영창1, 김현중2, Johannes Gierschner3, 이원주1, 권민상2
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| 소속 |
1한국화학(연), 2서울대, 3Madrid Institute for Advanced Studies |
| 키워드 |
Photocatalyst; Visible light; Pressure-sensitive adhesive
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| E-Mail |
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