화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 구조 및 물성
제목 Arrangement of Microdomain Structures of Block Copolymers Confined by Hemi-sphere
초록 The arrangement of the microdomains in block copolymers changes significantly compared with that in bulk, when they are confined at certain geometries (cylinders or spheres). Here, we study, via scanning and transmission electron microscopy, the changes of the microdomains of polystyrene-block-poly(methyl methacrylate) copolymer confined by hemi-sphere wall. This constraint was introduced by using anodic aluminum oxide template. The wall of hemi-sphere was treated by three different brush layers: (1) PS, (2) PMMA, and (3) neutral brushes. Many interesting morphologies which have not been reported are found.
저자 배두식1, 주원철2, 변진석2, 전금혜2, 김진곤2
소속 1포항공과대, 2포항공대
키워드 confined effect; ps-pmma
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