화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스))
권호 10권 2호
발표분야 정보전자소재
제목 The effect of AlF3 Coating on the High-Voltage Cycling Behavior of Li[Ni1/3Co1/3Mn1/3]O2 Cathode
초록 To improve the clcying performance of Li[Ni1/3Co1/3Mn1/3]O2 in high voltage range (3.0 - 4.5 or 3.0 - 4.6 V), The effect of AlF3-coating on electrochemical performance of was evaluated Li[Ni1/3Co1/3Mn1/3]O2. The SEM and TEM study showed a uniform AlF3-coating layer with a thickness of about 20nm on pristine Li[Ni1/3Co1/3Mn1/3]O2 particles. AlF3-coated Li[Ni1/3Co1/3Mn1/3]O2 shows significantly improved cycling performance compared to the pristine Li[Ni1/3Co1/3Mn1/3]O2. The AC impedance results showed that AlF3-coating formed a stable interface between positive electrode particles and electrolyte.
저자 조상우, 선양국
소속 한양대
키워드 AlF3; Coating; LiNi1/3Co1/3Mn1/3O2
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