화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 환경에너지_포스터
제목 Improved electrosorption capacity of ACF-based electrodes modified by oxyfluorination for capacitive deionization
초록 To increase electrosorption capacity and efficiency, there are many research concerning surface treatment of electrodes. In this study, fluorine functional group is introduced on a surface of activated carbon fiber (ACF), and it has a high negative charge due to its electronegativity. To introduce fluorine functional group on surface of ACF, ACF was modified by oxyfluorination using mixture gases of fluorine and oxygen with different partial pressure of F2: 0.1, 0.2, and 0.3 bar, and total pressure: 1 bar. The chemical composition changes of the untreated and oxyfluorinated ACFs were investigated using x-ray photoelectron spectroscopy. The CDI process was carried out at an electric potential of 0 ~ 1.2 V in 500 mg/L sodium chloride solution at 20 ml/min flow rate. The specific electrosorption capacity of optimized electrode (partial pressure of F2: 0.3 bar) was increased 116% compared to that of untreated electrode.
저자 김경훈, 조한주, 강다희, 이영석
소속 충남대
키워드 capacitive deionization; oxyfluorination; electrosorption
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