화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 가을 (10/31 ~ 11/02, 제주국제컨벤션센터(ICC JEJU))
권호 22권 2호
발표분야 무기재료_포스터
제목 Two-dimensional hybrid composites of rGO/La2Ti2O7/NiFe-LDH for highly efficient photocatalytic water splitting reaction
초록 We report a strategically designed heterojunction between three types of two-dimensional materials to promote efficient charge separation and to further optimize the water-splitting reaction via photocatalytic reaction without the usage of any noble metal cocatalysts. The material is composed of reduced graphene oxide (rGO) for the hydrogen evolution reaction cocatalyst, NiFe-layered double hydroxide (NiFe-LDH) for the oxygen evolution reaction cocatalyst, and lanthanum titanate (LTO) as the photocatalyst. The photo-generated charges from LTO are efficiently separated to rGO (electron sink) and NiFe-LDH (hole sink) for the water splitting reaction. Under the solar simulator (AM 1.5), the catalyst exhibited enhanced HER performances up to 9 times compared to the control sample. The mechanism of such high performance of the synthesized photocatalysts could be attributed to the efficient charge separation and longer lifetime of photogenerated charges.  
저자 Ramireddy Boppella1, 최치훈2, 문주호1, 김동하2
소속 1연세대, 2이화여자대
키워드 semiconductor photocatalyst; NiFe-LDH; rGO; hydrogen evolution
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