| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
포스터_에너지저장·변환 |
| 제목 |
Extrinsic Pseudocapacitive Features of Molecular-Level Controlled 2D Oxidized Black Phosphorus |
| 초록 |
Bulk and two-dimensional black phosphorus (BPs) are considered as the candidates for energy storage materials, but their performance are suffered by the low rate and cycling capabilities due to intrinsic (de-)alloying mechanism. In this work, we demonstrate the reversible extrinsic pseudocapacitive features on 2D oxidized BP (oBP) that are strongly hybridized with graphene. oBP-based electrodes show capacitance of 478 F g–1 with rate capability of 72% and retention of 91% over 50,000 cycles. The surface redox reaction at oxidized P sites was investigated by In-situ spectroelectrochemical and theoretical calculations. |
| 저자 |
puritut nakhanivej, 박재민, 박호석
|
| 소속 |
성균관대 |
| 키워드 |
Surface chemistry; Black phosphorus; Charge storage; Surface redox reaction; 2D hybrid; In-situ spectroscopy
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| E-Mail |
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