화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2017년 가을 (10/11 ~ 10/13, 제주컨벤션센터)
권호 42권 2호
발표분야 고분자구조 및 물성
제목 Phase behaviors of polymeric micelles by two different types polymers
초록 The amphiphilic block copolymers self-assemble into a nanoscale micellar structure in solution, and their phase behavior can be controlled by external conditions. Therefore, Pluronic block copolymers can applicable for template materials to fabricate a variety of nanostructures. For a wide range of use, however, we need to fabricate various nanostructures without complicated procedures. Furthermore, we investigated the phase behavior of Pluronic block copolymers into mixture solution at varying temperatures with the controlled other polymer concentration as an additives. Small angle neutron scattering(SANS) experimental results showed that Pluronic block copolymers in aqueous solution transformed into spheres, cylinders or vesicles when the temperature, concentration and additives increase. As the temperature increase with the controlled other polymer concentration lead to an increase of the hydrophobicity of the polymer and then occur to phase transition.
저자 장종대1, 방준하2, 한영수1, Anna Sokolova3, 김태환4
소속 1한국원자력(연), 2고려대, 3Australian Nuclear Science and Technology Organization, 4전북대
키워드 polymer; phase transition; self-assembly; micelle; neutron scattering
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