화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2018년 가을 (10/24 ~ 10/26, 대구 EXCO)
권호 24권 2호, p.1538
발표분야 에너지 환경(Energy and Environment)
제목 Excellent Biofouling Resistance of Triclosan-Immobilized Polyamide Thin Film Composite Membranes
초록 Polyamide (PA) thin film composite (TFC) used in the desalination process critically suffer from biofouling, which enhances the hydraulic resistance of the membrane, leading to its flux decline. In this work, to improve biofouling resistance of a PA TFC membrane, we propose a strategy to covalently immobilize a broad-spectrum organic biocide (triclosan, TC) on the membrane surface. TC was first functionalized with an aminopropyl group to improve its reactivity with the membrane surface and thus facilitate covalent attachment of TC. Then, the TC-immobilized TFC (TC-TFC) membranes were fabricated by the amide formation reaction between the amine groups of the aminopropyl-functionalized TC and the acyl chloride groups on the membrane surface, which was verified by XPS analysis. Although the hydrophobic nature of TC resulted the slightly reduced separation performance of the TC-TFC membrane, it still maintained a satisfactory RO performance level. Importantly, the TC-TFC membrane exhibited the strong antibacterial activity against both gram negative and gram positive bacteria and effectively retarded the biofilm formation on the membrane surface.
저자 박상희, 전성권, 박성준, 권순진, 신민규, 이정현
소속 고려대
키워드 에너지 환경
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