| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.2374 |
| 발표분야 | 촉매 및 반응공학 |
| 제목 | Selective heterogenous catalytic trimerization of xylose-derived furfural and 2-methylfuran to diesel precursors on a continuous fixed-bed reactor |
| 초록 | The valorization of xylose and the condensation of furfural and 2-methylfuran (2-MF), obtained by the dehydration and selective hydrogenation of xylose, to produce high-carbon-number hydro-carbons. Thus, environmentally friendly catalysts exhibiting comparable activities will help in the development of economically benign processes. 2-methylfuran is the selective hydrogenation product of furfural, which can be produced in industrial scale with lignocellulose. In this work, renewable diesel precursors were synthesized simultaneously by the solvent-free hydroxyalkylation/alkylation(HAA) followed by hydrodeoxygenation(HDO). The catalytic trimerization of 2-methylfuran was performed to produce diesel precusors of C15 hydro-carbons using solid acid catalysts that can replace environmentally harmful sulfuric acid. Among the solid acid catalysts used in this work, Amberlyst-15 exhibited the best activity and selectivity for the HAA of 2-MF. |
| 저자 | 권지선1, 황인환1, 최재욱1, 서동진1, 하정명1, 이관영2 |
| 소속 | 1한국과학기술(연), 2고려대 |
| 키워드 | 고체산촉매 |
| 원문파일 | 초록 보기 |
