| 학회 |
한국공업화학회 |
| 학술대회 |
2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구)) |
| 권호 |
13권 1호 |
| 발표분야 |
고분자 |
| 제목 |
The Anionic Oligomerization of Hexafluoropropylene using Cesium Fluoride as Catalyst |
| 초록 |
Hexafluoropropylene (HFP) oligomer such as dimer, trimer, and tetramer will be used as the reaction diluent for synthesis of perfluoropolyether or good fluoro-solvent. In this study, we report on anionic oligomerization of HFP initiated by cesium fluoride (CsF). HFP oligomer is synthesized by the combination of cesium fluoride, HFP and organic polar solvent such as tetraglyme, acetonitrile, and 1,4-dioxane. Synthesized oligomer was characterized by gel permeation chromatography (GPC) and gas chromatography (GC). The detailed experimental resultswill be described. |
| 저자 |
이상구1, 하종욱1, 박인준1, 이수복1, 이종대2
|
| 소속 |
1한국화학(연), 2충북대 |
| 키워드 |
hexafluoropropylene; oligomerization; cesium fluoride
|
| E-Mail |
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