화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 기능성 고분자
제목 Highly-bendable, proton-conductive silicate glass electrolytes integrated with polyimide nonwoven fabrics for medium-temperature/low-humidity proton exchange membrane fuel cells
초록 The highly-bendable, proton-conductive silicate glass electrolyte integrated with the PI nonwoven fabric (b-SS glass electrolyte) has been developed for potential use in medium-temperature/low-humidity PEMFCs. The b-SS glass electrolytes are fabricated via in-situ sol-gel synthesis of 3-trihydroxysilyl-1-propanesulfonic acid (THPSA)/3-glycidyloxypropyl trimethoxysilane (GPTMS) mixtures inside PI nonwoven substrates serving as a porous reinforcing framework. Owing to this structural uniqueness, the b-SS glass electrolytes provide noticeable improvements in mechanical bendability and membrane thickness, in comparison to typical bulk silicate glass electrolytes that are thick and easily fragile. Another salient feature of the b-SS glass electrolytes is the excellent proton conductivity at harsh measurement conditions of medium-temperature/low-humidity, which is highly important for PEMFC-powered electric vehicle (EV) applications.
저자 이현지1, 원지혜2, 임준묵2, 김정환1, 홍영택3, 이무석4, 이상영1
소속 1울산과학기술대, 2강원대, 3한국화학(연), 4코오롱인더스트리(주)
키워드 PEMFCs; bendable silicate glass electrolytes; polyimide nonwoven fabrics; THPSA/GPTMS; proton conductivity; medium-temperature/low-humidity
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