화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 기능성 고분자
제목 Photoluminescence of Ag@Polydiacetylene Shell Hybrid Nanoparticles with Different Ag Shapes
초록 Polydiacetylene (PDA) is a conjugated polymer which consists of blue-to-red color transition as well as non-fluorescence to fluorescence characteristic. In this study, Ag core/polydiacetylene shell hybrid nanoparticles are fabricated into spherical and cubic shape, respectively. The formation of the core-shell was analyzed using high-resolution transmission electron microscope (HR-TEM). As a result, the range of core-shell size was from 30 nm to 60 nm while the thickness of PDA shell turned out to be approximately 5 nm. Correlated confocal/atomic force microscopy has also been used to obtain photoluminescence (PL) spectra of isolated single core-shell nanoparticles. Compared to spherical core-shell, the cubic shaped ones evidently contained much stronger fluorescent signal. It is believed that the lightning rod at the edge of the cubic core-shell ultimately enhanced the fluorescence signal of PDA surrounded.
저자 이세라1, 최춘식1, 이은별2, 홍종욱3, 한상우3, 김지환2, 안동준1
소속 1고려대, 2서울대, 3KAIST
키워드 polydiacetylene; Ag; Hybrid nanoparticles
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