화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 고분자_포스터
제목 Synthesis of an Ionic Polyacetylene Derivative with the Long Alkyl Substituents via the Non-catalyst Polymerization of 2-Ethynylpyridine Using 1-Bromooctadecane
초록 Various ionic polyacetylenes have been prepared through the non-catalyst polymerization of ethynylpyridines with alkyl halides. The polymerization of 2-ethynylpyridine using 1-bromooctadecane yield the resulting poly(2-ethynyl-N-octadecylpyridinium bromide) in high yield. The polymer structure  was characterized to have an ionic conjugated polymer backbone with the designed substituent. The cyclic voltamogram of polymer exhibited that this material shows the well-defined and stable redox process and there was no characteristic change such as the increase of current density.

 
저자 이하윤1, 제갈영순2, 진성호3, 임권택4, 박종욱1
소속 1가톨릭대, 2경일대, 3부산대, 4부경대
키워드 Polyacetylene; 2-ethynylpyridine; octadecyl; characterization; photoluminescence
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