화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2012년 봄 (05/09 ~ 05/11, 김대중컨벤션센터)
권호 16권 1호
발표분야 에너지저장.변환
제목 Preparation and characterization of optical properties of the core-shell structured ZnS nanoparticles
초록 ZnS nanopartices (NPs) have attracted much attention during the last decade due to their luminescent properties. In this study, ZnS NPs on the monodispersed spherical silica NPs (ZnS@Silica, ZnS NPs weighed from 1 wt % to 16 wt % of ZnS based on the amount of silica used) were synthesized and covered with silica layer on their surface (Silica@ZnS@Silica). In PL analysis, PL intensities of ZnS@Silica NPs were increased to 1 ->8 wt %, but it decreased at more than 8 wt %. These results can be understood by electronic coupling and photoinduced electron transfer.  Their optical properties, structure analysis and surface morphology observation were investigated by PL instrument, UV-Vis spectrophotometer, XRD, SEM and HR-TEM respectively.
저자 강민수1, 한준수1, 황영애2, 유복렬1
소속 1한국과학기술(연), 2상명대
키워드 PL intensity; Red shift; Electronic coupling; Photoinduced electron transfer
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