학회 |
한국화학공학회 |
학술대회 |
2003년 봄 (04/25 ~ 04/26, 순천대학교) |
권호 |
9권 1호, p.1130 |
발표분야 |
촉매/반응공학 |
제목 |
Selective Catalytic Reduction (SCR) of Lean NOx using Hydrocarbon by Plasma Enhanced Catalysis over Nano-Size Gold Catalyst Supported on Alumina |
초록 |
Nano-sized gold catalysts supported on alumina were prepared and applied to the lean DeNOx reaction by plasma-enhanced catalysis. The average size of metallic gold particles estimated by dark field TEM analysis was 4.5 nm. The plasma-Au/Al2O3 system showed an improved DeNOx activity at low temperatures below 250℃. In case of plasma-2.0wt%Au/Al2O3, NOx conversion was about 40% and N2 yield was 10~30% at 100~250℃. The NOx reduction activity to N2 using hydrocarbon reductant at this temperature range has not been reported yet. This low-temperature DeNOx activity seems to be caused by the increase of Au - alumina interface due to the formation of nano-sized Au particles, which facilitated plasma-activated NO2 and hydrocarbon being adsorbed on the metallic Au and alumina, respectively, migrated and then reacted with each other. |
저자 |
이관영1, 이대원2, 류재홍2, 정동훈2, 이형상3, 전광민3
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소속 |
1고려대, 2(주)블루플래닛, 3연세대 |
키워드 |
SCR; NOx; Plasma; Catalysis; Nano; Gold; Alumina
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E-Mail |
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VOD |
VOD 보기 |