| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 가을 (10/11 ~ 10/12, 일산킨텍스) |
| 권호 |
32권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Copolymerization of Ethylene oxide, Epichlorohydrin and Tetrahydrofuran using Cationic Ring-Opening Polymerization |
| 초록 |
The well-defined terpolymers derived from ethylene oxide(EO), epichlorohydrin(ECH), and tetrahydrofuran(THF) were synthesized by the cationic ring-opening polymerization with 1,4-butandiol, a initiator, and BF3∙THF Complex, a catalyst system. This polymerization was proceeded by activated monomer (AM) mechanism for controlling the molecular weight, narrow molecular weight distribution, and the functionality. The structure and composition of synthesized terpolymers as well as ratio of 1° alcohol and 2° alcohol, hydroxyl end-groups were converted into the ester groups by reaction with trifluoroacetic anhydride(CF3CO)2O, were characterized by 1H-NMR spectroscopy. The molecular weight and the molecular weight distribution of their terpolymers were analyzed by gel-permeation chromatography (GPC). |
| 저자 |
신범식, 이범재, 이정환, 유호준, 김나리, 김두환, 이종섭, 김태중, 정권영
|
| 소속 |
충남대 |
| 키워드 |
Poly(EO-co-ECH-co-THF); Cationic Ring-Opening Polymerization; AM Mechanism
|
| E-Mail |
|
