| 학회 |
한국고분자학회 |
| 학술대회 |
2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터) |
| 권호 |
36권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis and characterization of partially fluorinated poly (arylene ether sulfone) containing cross-linkable moieties. |
| 초록 |
Poly(arylene ether sulfone) are well known engineering thermoplastics with many desirable properties such as excellent mechanical strength, high thermal and thermo-oxidative stabilities. Partially fluorinated poly(arylene ether sulfone) copolymers containing cross-linkable moieties were prepared via nucleophilic substitution reaction. The chemical structures of the synthesized copolymers were confirmed by 1H NMR and FTIR-ATR spectra. Cross-linked polymers were obtained by thermal curing of the cross-linkable copolymers. The thermal properties of the cross-linked polymers analyzed by TGA and DSC were considerably improved due to the formation of three-dimensional networks between polymer chains. The cross-linking degree of the cross-linked copolymers was determined by a solvent extraction. The formation of cross-linking structures in the polymer matrix can be important for proton exchange membrane fuel cells with improved properties. |
| 저자 |
이정수, 안효진, 장지현
|
| 소속 |
울산과학기술대 |
| 키워드 |
poly(arylene ether sulfone); cross-linking; thermal properties
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| E-Mail |
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