| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
분자전자 부문위원회 Ⅰ,Ⅱ |
| 제목 |
Large-area synthesis of ultra-thin, flexible and conductive Metal-Organic Frameworks thin-film via microfluidic-based solution shearing process |
| 초록 |
Amongst the c-MOFs, Ni3(hexaiminotriphenylene)2 (Ni3(HITP)2) is especially promising due to its high conductivity on the order of 4-5,000 S/m. We demonstrate a combination of the Microfluidic-based Solution shearing process and the Post-synthesis process (MSP) that enables the large-area synthesis of ultrathin, flexible, and conductive Ni3(HITP)2 films across micrometer-scale areas through precisely controlled steps. The continuous microfluidic flow in the microfluidic channel precisely mixes the precursors to supply a solution of uniform concentration during the solution shearing process. The homogeneous Ni3(HITP)2 precursor obtained from the solution shearing process forms the Ni3(HITP)2 thin-film after the amine post-treatment process. The resulting high qualities of the Ni3(HITP)2 thin-film facilitate its application in high-performance electronic devices. |
| 저자 |
이태훈, 스티브박
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| 소속 |
한국과학기술원 |
| 키워드 |
Conductive metal-organic frameworks; Microfluidic; Solution shearing; Ni3(HITP)2
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| E-Mail |
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