| 학회 |
한국공업화학회 |
| 학술대회 |
2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터) |
| 권호 |
17권 2호 |
| 발표분야 |
포스터-고분자 |
| 제목 |
Synthesis and characterization of poly(epichlorohydrin-co-1,2-butylene oxide) by cationic ring opening polymerization using a tripropylene glycol initiator in toluene solvent |
| 초록 |
The synthesis of polymeric materials with improved properties and performance has become an attractive field of polymer science. copolymers that provide specific combinations of thermal and physical properties are the suitable materials with good performance toward extreme environmental conditions such as low temperatures and high impact condition, etc. in this study poly(epichlorohydrin-co-1,2-butylene oxide) was synthesized via cationic ring-opening polymerization using boron trifluoride etherate as catalyst and toluene as the solvent for the copolymerization using tripropylene glycol initiator system was used. the polymer with different molar ratio of alkylene oxide monomers and epichlorohydrin monomer were synthesized under conditions of 5℃ for 20h in Toluene solvent. polymer characterization were performed by 1H-NMR, DSC and GPC. |
| 저자 |
이재명, 노시태, 권정옥, 조봉상, 김정수
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| 소속 |
한양대 |
| 키워드 |
cationic polymerization; TPG
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| E-Mail |
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