화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터)
권호 46권 1호
발표분야 고분자합성
제목 Porous Au-Ag-Ag2S Bimetal-Semiconductor Hybrid Nanostructures with Well-defined Nanocavities for High-efficiency Catalytic and Photothermal Activities
초록 Hybrid nanostructures comprising plasmonic noble metal and semiconductor have attracted attention owing to their novel properties and potential applications. However, the facile synthesis of these hybrid nanostructures with well-defined heterostructures and high porosity still remains challenging. Herein, we report a facile method for preparing porous triangular Au-Ag-Ag2S bimetal-semiconductor hybrid nanostructures. Following the selective etching of Ag in the Ag-Ag2S hybrid nanostructures, Au was deposited in a controlled manner. Using triangular Ag-Ag2S hybrid nanoplates with new heterostructures as templates and introducing an additional reducing agent in the galvanic replacement reaction with HAuCl4, the prepared Au-Ag-Ag2S had a porous structure, with plasmonic nanocavities on their surfaces and high absorbance in the visible and near-infrared regions. These hybrid nanostructures exhibited enhanced catalytic performance and very high photothermal conversion properties.
저자 Pradyasti Astrini, 김문호
소속 부경대
키워드 noble metal-semiconductor hybrid nanostructures; silver nanoplates; site-selective sulfidation; galvanic replacement reaction; catalytic degradation; photothermal
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