화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 가을 (11/02 ~ 11/04, 경원대학교)
권호 15권 2호
발표분야 무기재료
제목 Effect of direct fluorination on carbon molecular sieve for CH4/CO2 gas separation
초록 In this study, surface modified carbon molecular sieve (CMS) was prepared bydirect fluorination to investigate the separation behavior of CH4/CO2. The direct fluorination was carried out at various partial pressures. The effects ofdirect fluorination on the chemical components and the change of pore structure of CMSs were investigated by x-ray photoelectron spectra (XPS) and pore size distribution with CO2 gas. In addition the CO2 adsorption capacity was measured at absolute pressures of 0-800 mmHg and at temperatures of273 and 298 K. To investigate the characteristics of CO2/CH4 gas separation, micro gas chromatographic analysis was performed with mixed gas and nitrogen, and was studied about CO2/CH4 gas separation behavior.
저자 유혜련1, 조세호1, 배병철1, 장진석2, 이광복1, 이영석1
소속 1충남대, 2충청북도 중소기업청
키워드 carbon molecular sieve; direct fluorination; pore size distribution; CO2 adsorption; CH4/CO2 gas separation
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