| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
대학원생 구두발표 |
| 제목 |
Benzotriazole-Based Donor-Acceptor Type Semiconducting Polymers for Photovoltaic Devices |
| 초록 |
A series of low band gap polymers composed of benzotriazole and benzo[1,2-b:4,5-b']dithiophene (BDT) derivatives were synthesized using a Stille cross-coupling ewaction for use in organic photovoltaic devices. Linear or branched alkyl groups were incoporated into the benzotriazole-based accepting monomer part, and alkoxy or alkylthiophene groups were introduced to BDT-based donating monomer part. Changes in photo-pysical properties of the polymers by the structural modification of the donor-acceptor type low band gap polymers were inverstigated. The optical band gap energies of the polymers were measured to be 2.03-1.90 eV depending on the polymer structure. Solution-processed field-effect transistors were fabricated and characterized using the polymers as p-type channel materials. Bulk hetero-junction photovoltaic devices were fabricated using the polymers with PC71BM as the electron acceptor. |
| 저자 |
김지훈1, 김희운1, 송창은2, 신원석3, 강인남4, 이진균5, 황도훈1
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| 소속 |
1부산대, 2카이스트, 3한국화학(연), 4카톨릭대, 5인하대 |
| 키워드 |
Organic photovoltaic device; benzo[1; 2-b:4; 5-b’]dithiophene; benzotriazole; low band gap polymer
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| E-Mail |
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